At $600 \ K$,ammonium carbamate decomposes in a closed vessel: $NH_2COONH_{4(s)} \rightleftharpoons 2NH_{3(g)} + CO_{2(g)}$. At equilibrium,the total pressure is $3 \ bar$. Calculate $K_p$. (in $bar^3$)

For which of the following reactions will $K_p < K_c$?

For the reaction $N_2 + O_2 \rightleftharpoons 2NO$ at $300 \, ^\circ C$,the value of $K_c$ is $9 \times 10^{-4}$. If equivalent amounts of $N_2$ and $O_2$ are used,what is the concentration of $NO$ at equilibrium (in terms of $a$) (in $, a$)?

For a given reaction,$2 A \rightleftharpoons B + C$,the equilibrium constant is $2 \times 10^{-3}$. If at any given time the composition of the reaction mixture is $[A]=[B]=[C]=6 \times 10^{-5} \ M$; predict in which direction the reaction will proceed and the correct value for reaction quotient.

Given three reactions and their equilibrium constants:
$N_2 + 3H_2 \rightleftharpoons 2NH_3 ; k_1$
$N_2 + O_2 \rightleftharpoons 2NO ; k_2$
$H_2 + \frac{1}{2}O_2 \rightleftharpoons H_2O ; k_3$
The equilibrium constant for the reaction $2NH_3 + \frac{5}{2}O_2 \rightleftharpoons 2NO + 3H_2O$ in terms of $k_1, k_2,$ and $k_3$ is:

Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per the following endothermic reaction:
$CH_{4(g)} + H_2O_{(g)} \rightleftharpoons CO_{(g)} + 3H_{2(g)}$
$(a)$ Write an expression for $K_p$ for the above reaction.
$(b)$ How will the values of $K_p$ and the composition of the equilibrium mixture be affected by:
$(i)$ increasing the pressure
$(ii)$ increasing the temperature
$(iii)$ using a catalyst?