Assertion: Phenol undergoes Kolbe reaction,et | vedclass

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(C) The Kolbe reaction involves the reaction of sodium phenoxide with $CO_2$ under pressure followed by acidification to form salicylic acid. This rea

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If the Assertion is correct but Reason is incorrect.

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(C) The Kolbe reaction involves the reaction of sodium phenoxide with $CO_2$ under pressure followed by acidification to form salicylic acid. This reaction is specific to phenols because the phenoxide ion is resonance-stabilized,making the ring electron-rich and susceptible to electrophilic attack by $CO_2$.Ethanol does not undergo this reaction because it does not form a stable phenoxide-like intermediate. Thus,the Assertion is true.Regarding the Reason,the phenoxide ion $(C_6H_5O^-)$ is significantly less basic than the ethoxide ion $(C_2H_5O^-)$. This is because the negative charge on the phenoxide ion is delocalized into the benzene ring via resonance,whereas the ethoxide ion has no such stabilization and the alkyl group $(C_2H_5-)$ is electron-donating,which increases the electron density on the oxygen atom.Therefore,the Reason is incorrect.

Assertion: Phenol undergoes Kolbe reaction,ethanol does not.
Reason: Phenoxide ion is more basic than ethoxide ion.

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Assertion: Phenol undergoes Kolbe reaction,ethanol does not.Reason: Phenoxide ion is more basic than ethoxide ion.