An organic compound $A$ is oxidized using acidified $K_2Cr_2O_7$ solution to form compound $B$. Compound $B$ gives the $DNP$ test but not the silver mirror test. Then,compound $A$ is:

  • A
    $2-$propanol
  • B
    $1-$propanol
  • C
    ethanal
  • D
    ethanol

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What will be the product obtained when formaldehyde is treated with conc. $NaOD$ followed by treatment with conc. $H_2SO_4$?

Match the example given in Column-$I$ with the name of the reaction in Column-$II$.
Column-$I$ (Example)Column-$II$ (Reaction)
$(A)$ $CH_3COCl + H_2 \xrightarrow{Pd-C/BaSO_4} CH_3CHO$$(1)$ Friedel-Crafts acylation
$(B)$ $C_6H_5CHO \xrightarrow{NaOH} C_6H_5CH_2OH + C_6H_5COONa$$(2)$ $HVZ$ reaction
$(C)$ $C_6H_6 + CH_3COCl \xrightarrow{AlCl_3} C_6H_5COCH_3$$(3)$ Aldol condensation
$(D)$ $R-CH_2COOH \xrightarrow{Br_2/Red P} R-CH(Br)COOH$$(4)$ Cannizzaro's reaction
$(E)$ $CH_3-CN \xrightarrow{SnCl_2/HCl, H_2O/H^+} CH_3-CHO$$(5)$ Rosenmund's reduction
$(F)$ $2CH_3CHO \xrightarrow{NaOH} CH_3-CH=CH-CHO$$(6)$ Stephen's reaction

In the scheme given below,the total number of intra molecular aldol condensation products formed from '$Y$' is

Give the reaction of $(a)$ acetaldehyde and $(b)$ acetone with $(i)$ $NaHSO_{3}$ and $(ii)$ $HCN$.

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