An organic acid $P$ $(C_{11}H_{12}O_2)$ can easily be oxidized to a dibasic acid which reacts with ethylene glycol to produce a polymer,dacron. Upon ozonolysis,$P$ gives an aliphatic ketone as one of the products. $P$ undergoes the following reaction sequences to furnish $R$ via $Q$. The compound $P$ also undergoes another set of reactions to produce $S$.
$(1)$ The compound $R$ is
$(2)$ The compound $S$ is
Give the answer for questions $(1)$ and $(2)$.

  • A
    $A, C$
  • B
    $A, B$
  • C
    $A, D$
  • D
    $A, C, D$

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What are $\underline{A}, \underline{B}, \underline{C}$ in the following reactions?
$(I)$ $(CH_3 CO_2)_2 Ca \stackrel{\Delta}{\longrightarrow} \underline{A}$
$(II)$ $CH_3 CO_2 H \underset{\text{Red P}}{\stackrel{HI}{\longrightarrow}} \underline{B}$
$(III)$ $2 CH_3 CO_2 H \stackrel{P_4 O_{10}}{\longrightarrow} \underline{C}$
$\underline{A} \quad \underline{B} \quad \underline{C}$

Match the reactions given in Column-$I$ with their products in Column-$II$.
Column-$I$ (Reactant) Column-$II$ (Product)
$A$. $RCH_2OH \xrightarrow[(ii) H_3O^{+}]{(i) NaOH, KMnO_4} ?$ $i$. $C_6H_5COOH + C_2H_5OH$
$B$. $CH_3(CH_2)_8CH_2OH \xrightarrow{Jones reagent} ?$ $ii$. $RCOOH$
$C$. $RCONH_2 \xrightarrow{H_3O^{+}, \Delta} ?$ $iii$. $CH_3(CH_2)_8COOH$
$D$. $C_6H_5COOEt \xrightarrow{H_3O^{+}} ?$ $iv$. $RCOOH + NH_3$

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Ethanol on reaction with alkaline $KMnO_4$ gives $X$,which when reacted with methanol in the presence of an acid gives a sweet-smelling compound $Y$. $X$ and $Y$ respectively are:

Ethyl ester $\xrightarrow{CH_3MgBr \text{ (excess)}} P$. The product $P$ will be

An ester $(A)$ with molecular formula $C_9H_{10}O_2$ is reacted with an excess of $CH_3MgBr$. The resulting product is treated with concentrated $H_2SO_4$ to form an olefin $(B)$. Ozonolysis of $(B)$ yields a ketone with the formula $C_8H_8O$. What is the structure of $(A)$?

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