An aqueous solution of $FeSO_4$,$Al_2(SO_4)_3$ and chrome alum is heated with excess of $Na_2O_2$ and filtered. The materials obtained are

  • A
    $A$ colourless filtrate and a green residue
  • B
    $A$ yellow filtrate and a green residue
  • C
    $A$ yellow filtrate and a brown residue
  • D
    $A$ green filtrate and a brown residue

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Identify the reactions in which dichromate acts as an oxidising reagent.
$I$. $Cr_2O_7^{2-} + 6Fe^{2+} + 14H^{+} \longrightarrow 2Cr^{3+} + 6Fe^{3+} + 7H_2O$
$II$. $Cr_2O_7^{2-} + 2OH^{-} \longrightarrow 2CrO_4^{2-} + H_2O$
$III$. $Cr_2O_7^{2-} + 6I^{-} + 14H^{+} \longrightarrow 2Cr^{3+} + 3I_2 + 7H_2O$
$IV$. $Na_2Cr_2O_7 + 2KCl \longrightarrow K_2Cr_2O_7 + 2NaCl$

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