An acidic buffer is obtained on mixing

  • A
    $100 \ mL$ of $0.1 \ M \ CH_3COOH$ and $200 \ mL$ of $0.1 \ M \ NaOH$
  • B
    $100 \ mL$ of $0.1 \ M \ CH_3COOH$ and $100 \ mL$ of $0.1 \ M \ NaOH$
  • C
    $100 \ mL$ of $0.1 \ M \ HCl$ and $200 \ mL$ of $0.1 \ M \ CH_3COONa$
  • D
    $100 \ mL$ of $0.1 \ M \ HCl$ and $200 \ mL$ of $0.1 \ M \ NaCl$

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The $pH$ of a buffer solution containing $25 \ mL$ of $1 \ M \ CH_3COONa$ and $25 \ mL$ of $1 \ M \ CH_3COOH$ will be appreciably affected by $5 \ mL$ of

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