Amongst the following solutions,the buffer solution is

Calculate the $pH$ of a buffer solution containing $0.01 \ M$ salt and $0.004 \ M$ weak acid. $(pK_{a} = 4.762)$

Which of the following is a buffer solution of strong acidic nature?

Calculate the $pH$ of a buffer solution containing $0.027 \ M$ weak acid and $0.054 \ M$ of its salt with a strong base,if the $pK_{a}$ is $4.2$.

The $pH$ of an aqueous solution containing $1 \ M$ benzoic acid $(pK_{a}=4.20)$ and $1 \ M$ sodium benzoate is $4.5$. The volume of benzoic acid solution in $300 \ mL$ of this buffer solution is . . . . . . $mL$.

The $pH$ of a buffer solution decreases by $0.02$ units when $0.12 \ g$ of acetic acid is added to $250 \ mL$ of a buffer solution of acetic acid and potassium acetate at $27^{\circ} C$. The buffer capacity of the solution is