Amongst the following,the most stable complex is:
$(i)$ $[Fe(H_2O)_6]^{3+}$
$(ii)$ $[Fe(NH_3)_6]^{3+}$
$(iii)$ $[Fe(C_2O_4)_3]^{3-}$
$(iv)$ $[FeCl_6]^{3-}$

  • A
    $(i)$
  • B
    $(ii)$
  • C
    $(iii)$
  • D
    $(iv)$

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Similar Questions

$A$ solution containing $2.675 \ g$ of $CoCl_3 \cdot 6 NH_3$ (molar mass $= 267.5 \ g \ mol^{-1}$) is passed through a cation exchanger. The chloride ions obtained in solution were treated with excess of $AgNO_3$ to give $4.78 \ g$ of $AgCl$ (molar mass $= 143.5 \ g \ mol^{-1}$). The formula of the complex is
(At. mass of $Ag = 108 \ u$)

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$CrCl_3 \cdot xNH_3$ can exist as a complex. $A$ $0.1 \ m$ aqueous solution of this complex shows a depression in freezing point of $0.558^{\circ} C$. Assuming $100 \%$ ionisation of this complex and that the coordination number of $Cr$ is $6$,the complex will be: (Given $K_f = 1.86 \ K \ kg \ mol^{-1}$)

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