$A$ rather interesting example of the Wolff rearrangement with $2$-diazocyclohexanone in methanol is given below. Identify the major product.

  • A
    Cyclopentanecarboxylic acid methyl ester
  • B
    $2$-methoxycyclohexanone
  • C
    Cyclohexane-$1,2$-dione
  • D
    Cyclopentanecarboxylic acid

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$II. CH_3-CO-CH_3 \xrightarrow{HCN/OH^-} CH_3-C(OH)(CN)-CH_3$
$III. CH_3-CH_2-CH_3 \xrightarrow{Cl_2/h\nu} CH_3-CHCl-CH_3$

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Match Column-$I$ and Column-$II$ with the correct relation:
Column-$I$ Column-$II$
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$(ii)$ Addition reaction $(q)$ $C_6H_6 + NO_2^+ \to C_6H_5NO_2 + H^+$
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In the following reaction,compound $Q$ is obtained from compound $P$ via an ionic intermediate. What is the degree of unsaturation of $Q$?

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