$A$ first order reaction takes $40 \ min$ for $30 \%$ decomposition. Calculate $t_{1/2}$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) For a first order reaction,the rate constant $k$ is given by:
$k = \frac{2.303}{t} \log \frac{[R]_0}{[R]}$
Given $t = 40 \ min$ and $[R] = [R]_0 - 0.30[R]_0 = 0.70[R]_0$,
$k = \frac{2.303}{40} \log \frac{100}{70} = \frac{2.303}{40} \log(1.4286)$
$k = \frac{2.303}{40} \times 0.1549 = 8.918 \times 10^{-3} \ min^{-1}$
Now,the half-life $t_{1/2}$ is calculated as:
$t_{1/2} = \frac{0.693}{k} = \frac{0.693}{8.918 \times 10^{-3}} \ min$
$t_{1/2} \approx 77.7 \ min$

Explore More

Similar Questions

Azo-isopropane decomposes according to the following equation:
$((CH_3)_2CHN = NCH(CH_3)_2)_{(g)} \xrightarrow{250 - 290 ^oC} (N_2)_{(g)} + (C_6H_{14})_{(g)}$
It is a first-order reaction. If the initial pressure is $P_o$ and the total pressure of the mixture at time $t$ is $P_t$,find the rate constant $K$.

Difficult
View Solution

Time required to decompose $SO_{2}Cl_{2}$ to half of its initial amount is $60 \ minutes$. If the decomposition is a first order reaction,calculate the rate constant of the reaction.

Which among the following represents the expression for the $\left(\frac{3}{4}\right)^{\text{th}}$ life of a $1^{\text{st}}$ order reaction?

The rate constant for a first-order reaction is $0.02232 \ min^{-1}$. Calculate the time required for $75 \%$ completion of the reaction. (in $min$)

Consider the first-order gas-phase decomposition reaction given below:
$A_{(g)} \longrightarrow B_{(g)} + C_{(g)}$
The initial pressure of the system before the decomposition of $A$ was $P_i$. After time $t$,the total pressure of the system increased by $x \ units$ and became $P_t$. The rate constant $k$ for the reaction is given as:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo