$Ph-CO-CH_3 \xrightarrow[H_2O]{Mg-Hg}$ Product. The main product is:

  • A
    $Ph-CO-CO-Ph$
  • B
    $CH_3-CO-CO-CH_3$
  • C
    $Ph-C(OH)(CH_3)-C(OH)(CH_3)-Ph$
  • D
    $Ph-CO-C(Ph)(CH_3)_2$

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Match the reactions in Column $I$ with appropriate options in Column $II$.
Column $I$ Column $II$
$A$. $Ph-N_2Cl + Ph-OH \xrightarrow{NaOH/H_2O, 0^{\circ}C} Ph-N=N-Ph-OH$ $p$. Racemic mixture
$B$. $Pinacol \xrightarrow{H_2SO_4} Pinacolone$ $q$. Addition reaction
$C$. $Ph-CO-CH_3 \xrightarrow{1. LiAlH_4, 2. H_3O^+} Ph-CH(OH)-CH_3$ $r$. Substitution reaction
$D$. $4-chlorocyclohexanethiol \xrightarrow{Base} Thiacycloheptane$ $s$. Coupling reaction
$t$. Carbocation intermediate

The product obtained as a result of the reaction between acetone and chloroform is used as:

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$A$ compound,containing only carbon,hydrogen,and oxygen,has a molecular weight of $44$. On complete oxidation,it is converted into a compound of molecular weight $60$. The original compound is:

$CH_3-CHO \xrightarrow{NaOH + Cl_2} A + HCOONa$. Product $A$ can be used as:

Arrange the following compounds in increasing order of their reactivity towards $HCN$:
$I$. Acetaldehyde
$II$. Acetone
$III$. Di-tert-butyl ketone
$IV$. Methyl-tert-butyl ketone

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