What will be the major product $A$ in the following reaction?

  • A
    Option A
  • B
    Option B
  • C
    Option C
  • D
    Option D

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Assertion : $S_{N}2$ reaction of an optically active aryl halide with an aqueous solution of $KOH$ always gives an alcohol with opposite sign of rotation.
Reason : $S_{N}2$ reactions always proceed with retention of configuration.

Aryl halides are less reactive towards nucleophilic substitution reactions compared to alkyl halides because of:

Which among the following statements is true about the reactivity of haloarenes towards nucleophilic substitution reactions?
$1$. Haloarenes are very reactive towards nucleophilic substitution reaction.
$2$. In haloarenes,the $C-X$ bond acquires partial double bond character.
$3$. The $C-X$ bond in haloarenes is longer than the $C-X$ bond in haloalkanes.
$4$. In haloarenes,the phenyl cation formed as a result of self-ionisation is stable.

Match the reactants in Column-$I$ with their products in Column-$II$.
Column-$I$ (Reactants)Column-$II$ (Products)
$(A)$ $p$-Nitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 443 \ K}$$(i)$ Phenol
$(B)$ Chlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 623 \ K, 300 \ atm}$$(ii)$ $2,4,6$-Trinitrophenol
$(C)$ $2,4$-Dinitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 368 \ K}$$(iii)$ $2,4$-Dinitrophenol
$(D)$ $2,4,6$-Trinitrochlorobenzene $\xrightarrow{Warm \ H_2O}$$(iv)$ $p$-Nitrophenol

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The correct sequence of reagents used in the preparation of $4-$bromo$-2-$nitroethylbenzene from benzene is:

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