How can propyne and propene be distinguished?

  • A
    Conc. $H_2SO_4$
  • B
    $Br_2$ in $CCl_4$
  • C
    Dilute $KMnO_4$
  • D
    Ammoniacal $AgNO_3$

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Difficult
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$HC \equiv CH$ $\xrightarrow[{excess}]{{CH_3MgBr}} \mathop {(A)}\limits_{\text{salt}} + \mathop {(B)}\limits_{\text{hydrocarbon}}$
$(A)$ $\xrightarrow[{excess}]{{CH_3I}} (C)$ $\xrightarrow[{(ii) H^{+} }]{{(i) NaNH_2}} (D)$

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