For reaction-$I$,the reagents are $CH_3CONH_2, KOH, Br_2$. For reaction-$II$,the reagents are $CH_3NH_2, CHCl_3, KOH$. What are the intermediates for reaction-$I$ and reaction-$II$ respectively?

Aniline reacts with mixed acid (conc. $HNO_3$ and conc. $H_2SO_4$) at $288 \ K$ to give $P$ $(51 \%)$,$Q$ $(47 \%)$ and $R$ $(2 \%)$. The major product$(s)$ of the following reaction sequence is (are):
$R$ $\xrightarrow[2) Br_2, CH_3CO_2H]{1) Ac_2O, \text{pyridine}}$ $\xrightarrow{3) H_3O^+}$ $\xrightarrow{4) NaNO_2, HCl / 273-278 \ K}$ $\xrightarrow{5) EtOH, \Delta}$ $\xrightarrow{6) Sn/HCl}$ $\xrightarrow{7) Br_2/H_2O \text{ (excess)}} \text{Major Product}$

Nitrobenzene on reduction with zinc and $NH_4Cl$ gives:

$Ph-NH_2$ $\xrightarrow[Br_2]{HNO_2} A$ $\xrightarrow[Warm]{H_2O} B$
$B$ is

What is the major product of the following reaction?
$CH_3CH_2CH_2CH_2NH_2 \xrightarrow{HNO_2} ?$

What is the product of the following reaction?