What is the reduction potential of a silver wire dipped in a $0.1 \ M \ AgNO_3$ solution at $25^\circ C$?

  • A
    $E^o_{red}$
  • B
    $(E^o_{red} + 0.059)$
  • C
    $(E^o_{oxi} - 0.059)$
  • D
    $(E^o_{red} - 0.059)$

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The following reaction takes place at $298 \, K$ in an electrochemical cell involving two metals $A$ and $B$,
$A^{2+}_{(aq)} + B_{(s)} \rightarrow B^{2+}_{(aq)} + A_{(s)}$
with $[A^{2+}] = 4 \times 10^{-3} \, M$ and $[B^{2+}] = 2 \times 10^{-3} \, M$ in the respective half-cells,the cell $EMF$ is $1.091 \, V$.
The equilibrium constant of the reaction is closest to

The standard emf for the cell $Cd_{(s)}|Cd^{2+}_{(aq)}(1 \ M)||Cu^{2+}_{(aq)}(1 \ M)|Cu_{(s)}$ is $0.74 \ V$. If the concentration of $Cd^{2+}_{(aq)}$ and $Cu^{2+}_{(aq)}$ both decrease by $10$ times at $298 \ K$,calculate the emf of the cell.

Write the Nernst equation and calculate the $emf$ of the following cells at $298 \, K$:
$(i) \; Mg_{(s)} | Mg^{2+}(0.001 \, M) || Cu^{2+}(0.0001 \, M) | Cu_{(s)}$
$(ii) \; Fe_{(s)} | Fe^{2+}(0.001 \, M) || H^{+}(1 \, M) | H_{2(g)}(1 \, bar) | Pt_{(s)}$
$(iii) \; Sn_{(s)} | Sn^{2+}(0.050 \, M) || H^{+}(0.020 \, M) | H_{2(g)}(1 \, bar) | Pt_{(s)}$
$(iv) \; Pt_{(s)} | Br_{2(l)} | Br^{-}(0.010 \, M), H^{+}(0.030 \, M) || H_{2(g)}(1 \, bar) | Pt_{(s)}$

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Calculate the e.m.f. of the half-cell given below: $Fe | FeSO_4$ $(a = 0.1 \ M)$ where $E^o_{OP} = 0.44 \ V$. (in $V$)

At $298 \ K$,if the $emf$ of the cell corresponding to the reaction,$Zn_{(s)} + 2H^+_{(aq)} \rightarrow Zn^{2+}(0.01 \ M) + H_{2(g)}(1 \ atm)$ is $0.28 \ V$,then the $pH$ of the solution at the hydrogen electrode is (Given: $\frac{2.303 \ RT}{F} = 0.06 \ V$,$E^o_{Zn^{2+}|Zn} = -0.76 \ V$)

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