The standard electrode potentials of two half-cells are given as: $Ni^{2+}_{(aq)} + 2e^{-} \rightarrow Ni_{(s)}$; $E^o = -0.25 \ V$ and $Zn^{2+}_{(aq)} + 2e^{-} \rightarrow Zn_{(s)}$; $E^o = -0.76 \ V$. What is the standard $emf$ of the cell formed by connecting these two half-cells in $volt$?

  • A
    $-1.01$
  • B
    $+0.51$
  • C
    $+1.01$
  • D
    $-0.51$

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The $E^{0}_{Red}$ values for $P, Q, R$ and $S$ are $-2.90 \, V, +0.34 \, V, +1.20 \, V$ and $-0.76 \, V$ respectively. The decreasing order of their reactivity is:

Given the standard reduction potentials at $25\,^oC$ for the following half-reactions:
$Zn^{2+}_{(aq)} + 2e^- \rightleftharpoons Zn_{(s)}, E^o = -0.76\,V$
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$Fe^{3+}_{(aq)} + e^- \rightleftharpoons Fe^{2+}_{(aq)}, E^o = +0.77\,V$
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The reducing ability of the metals $K$,$Au$,$Zn$ and $Pb$ follows the order

For the cell reaction:
$2 Fe^{3+}_{(aq)} + 2 I^{-}_{(aq)} \rightarrow 2 Fe^{2+}_{(aq)} + I_{2(aq)}$
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