Which of the following orders is incorrect?

The Biuret test is not given by:

If a line makes angles $\tan ^{-1} \sqrt{7}$ and $\tan ^{-1} \frac{\sqrt{5}}{\sqrt{3}}$ with the $X$-axis and $Y$-axis respectively,then the angle made by it with the $Z$-axis is

Consider the following reaction equilibrium:
$N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$
Initially,$1 \text{ mole}$ of $N_2$ and $3 \text{ moles}$ of $H_2$ are taken in a $2 \text{ L}$ flask. At equilibrium state,if the number of moles of $N_2$ is $0.6$,what is the total number of moles of all gases present in the flask?

By what factor does the average velocity of a gaseous molecule increase when the temperature (in Kelvin) is doubled?

If $0 < x < 1$,then $\sqrt{1+x^2}\left[\left\{x \cos \left(\cot ^{-1} x\right)+\sin \left(\cot ^{-1} x\right)\right\}^2-1\right]^{1 / 2}$ is equal to