Which of the following reactions occurs during iodometric titration in the laboratory?

  • A
    $Cr_2O_7^{2-} + 14H^+ + 6I^- \to 2Cr^{3+} + 3I_2 + 7H_2O$; $I_2 + 2S_2O_3^{2-} \to S_4O_6^{2-} + 2I^-$
  • B
    $MnO_4^- + 8H^+ + 5I^- \to Mn^{2+} + 2.5I_2 + 4H_2O$; $I_2 + 2S_2O_3^{2-} \to S_4O_6^{2-} + 2I^-$
  • C
    $MnO_4^{2-} + OH^- + I^- \to MnO_2 + I_2$; $I_2 + 2S_2O_3^{2-} \to S_4O_6^{2-} + 2I^-$
  • D
    $Cr_2O_7^{2-} + OH^- + I^- \to 2Cr^{3+} + I_2$; $I_2 + 2S_2O_3^{2-} \to S_4O_6^{2-} + 2I^-$

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Similar Questions

An organic dye,eosin,used to detect the endpoint of precipitation titration by adsorption is called:

Given below are two statements:
Statement $I$: In the oxalic acid vs $KMnO_4$ (in the presence of dil. $H_2SO_4$) titration,the solution needs to be heated initially to $60^{\circ}C$,but no heating is required in Ferrous Ammonium Sulphate $(\text{FAS})$ vs $KMnO_4$ titration (in the presence of dil. $H_2SO_4$).
Statement $II$: In oxalic acid vs $KMnO_4$ titration,the initial formation of $MnSO_4$ takes place at high temperature,which then acts as a catalyst for the further reaction. In the case of $\text{FAS}$ vs $KMnO_4$,heating oxidizes $Fe^{2+}$ into $Fe^{3+}$ by oxygen of air and error may be introduced in the experiment.
In the light of the above statements,choose the correct answer from the options given below:

$5.00 \ mL$ of $0.10 \ M$ oxalic acid solution taken in a conical flask is titrated against $NaOH$ from a burette using phenolphthalein indicator. The volume of $NaOH$ required for the appearance of permanent faint pink color is tabulated below for five experiments. What is the concentration,in molarity,of the $NaOH$ solution?
$Exp. \ No.$ $Vol. \ of \ NaOH \ (mL)$
$1$ $12.5$
$2$ $10.5$
$3$ $9.0$
$4$ $9.0$
$5$ $9.0$

Can titrations with $KMnO_4$ be performed in the presence of $HCl$? Why?

The indicator used in the titration of $Na_2CO_3$ with $H_2SO_4$ is

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