The total pressure of a gas and a few drops of water in a container is $830 \, mm$. If the temperature of the container is decreased by $1 \%$,the new pressure is $............ \, mm$. The water vapor pressures at the two temperatures are $30 \, mm$ and $25 \, mm$ respectively.

Identify the incorrect statement among the following:

For a liquid,the normal boiling point is $-173\,^{\circ}C$. At $2\ atm$ pressure,its boiling point should be nearly ......... $^{\circ}C$. (Given: $\Delta H_{vap} = 200\ cal/mol$,$R = 2\ cal/mol\cdot K$,$\ln 2 = 0.7$)

Which one of the following statements is not correct?

$1 \text{ mole}$ of gas $A$ and $1 \text{ mole}$ of gas $B$ at $27^{\circ} C$ were pumped into a $24.6 \ L$ volume pre-evacuated isolated flask. The catalyst coated inside the flask catalyses the following reaction $A_{(g)} + B_{(g)} \longrightarrow 2 D_{(g)}$. The kinetic energy of $D$ is $98.03 \ L \ atm$. Calculate the pressure realized at the end of the reaction. (in $atm$)

Match gases under specified conditions listed in Column-$I$ with their properties/laws in Column-$II$.

Column-$I$	Column-$II$
$A$. Hydrogen gas $(P=200 \ atm, T=273 \ K)$	$p$. Compressibility factor $Z \neq 1$
$B$. Hydrogen gas $(P \approx 0, T=273 \ K)$	$q$. Attractive forces are dominant
$C$. $CO_2$ $(P=1 \ atm, T=273 \ K)$	$r$. $PV=nRT$
$D$. Real gas with very large molar volume	$s$. $P(V_m-b)=RT$