For the reaction $2Cl_{(g)} \rightarrow Cl_{2(g)}$,the signs of $\Delta H$ and $\Delta S$ are respectively:

An ideal gas is expanded from $(p_1, V_1, T_1)$ to $(p_2, V_2, T_2)$ under different conditions. The correct statement$(s)$ among the following is(are):
[$A$] The work done on the gas is maximum when it is compressed irreversibly from $(p_2, V_2)$ to $(p_1, V_1)$ against constant pressure $p_1$.
[$B$] The work done by the gas is less when it is expanded reversibly from $V_1$ to $V_2$ under adiabatic conditions as compared to that when expanded reversibly from $V_1$ to $V_2$ under isothermal conditions.
[$C$] The change in internal energy of the gas is $(i)$ zero,if it is expanded reversibly with $T_1=T_2$,and $(ii)$ positive,if it is expanded reversibly under adiabatic conditions with $T_1 \neq T_2$.
[$D$] If the expansion is carried out freely,it is simultaneously both isothermal as well as adiabatic.

The heat evolved during the combination of $24 \, g$ of $C$ and $128 \, g$ of $S$ according to the reaction $C + 2S \to CS_2$ with $\Delta H = 22.0 \, kcal$ is:

$2.4 \ g$ coal is burnt in a bomb calorimeter in excess of oxygen at $298 \ K$ and $1 \ atm$ pressure. The temperature of the calorimeter rises from $298 \ K$ to $300 \ K$. The enthalpy change during the combustion of coal is $-x \ kJ \ mol^{-1}$. The value of $x$ is. (Nearest Integer) (Given: Heat capacity of bomb calorimeter $20.0 \ kJ \ K^{-1}$. Assume coal to be pure carbon)

Total enthalpy change for freezing of $1 \ mol$ of water at $10^{\circ} C$ to ice at $-10^{\circ} C$ is $..........$ (Given : $\Delta_{fus} H = x \ kJ / mol$,$C_{p}[H_2O_{(l)}] = y \ J \ mol^{-1} \ K^{-1}$,$C_{p}[H_2O_{(s)}] = z \ J \ mol^{-1} \ K^{-1}$)

For the combustion of $1 \ mol$ of liquid benzene at $298 \ K$,the heat of reaction at constant pressure is $-3268 \ kJ \ mol^{-1}$. What is the heat of combustion at constant volume? $(R = 8.314 \times 10^{-3} \ kJ \ K^{-1} \ mol^{-1})$