Which of the following values of heat of formation (in $kcal$) indicates that the product is less stable?

If $C + O_2 \to CO_2 + 94.2 \ kcal$,$H_2 + \frac{1}{2} O_2 \to H_2O + 68.3 \ kcal$,and $CH_4 + 2O_2 \to CO_2 + 2H_2O + 210.8 \ kcal$,then the heat of formation of methane will be $... \ kcal$.

Calculate the enthalpy of solution of potassium chloride $(KCl)$ if its lattice enthalpy $\Delta_{L} H = 700 \ kJ \ mol^{-1}$ and hydration enthalpy $\Delta_{hyd} H = -680 \ kJ \ mol^{-1}$.

If at $298 \, K$ the bond energies of $C-H, C-C, C=C$ and $H-H$ bonds are respectively $414, 347, 615$ and $435 \, kJ \, mol^{-1}$,the value of enthalpy change for the reaction $H_2C=CH_{2(g)} + H_{2(g)} \to H_3C-CH_{3(g)}$ at $298 \, K$ will be $.... \, kJ$.

Calculate the heat of formation for propene $(C_3H_6)$ using the following thermochemical equations:
$(i) C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H_1 = -94.05 \ k.cal/mole$
$(ii) H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(l)}; \Delta H_2 = -68.32 \ k.cal/mole$
$(iii) C_3H_{6(g)} + \frac{9}{2} O_{2(g)} \to 3 CO_{2(g)} + 3 H_2O_{(l)}; \Delta H_3 = -499.7 \ k.cal/mole$
(Note: The original question provided propane combustion data; assuming propene combustion data for consistency).

The enthalpy of vaporisation of $CCl_4$ is $30.5 \ kJ \ mol^{-1}$. Calculate the heat required for the vaporisation of $284 \ g$ of $CCl_4$ at constant pressure. (Molar mass of $CCl_4 = 154 \ g \ mol^{-1}$).