Which of the following equations represents the standard enthalpy of formation of $CH_4$?

  • A
    $C(\text{diamond}) + 2H_{2(g)} \rightarrow CH_{4(g)}$
  • B
    $C(\text{graphite}) + 2H_{2(g)} \rightarrow CH_{4(g)}$
  • C
    $C(\text{diamond}) + 4H_{(g)} \rightarrow CH_{4(g)}$
  • D
    $C(\text{graphite}) + 4H_{(g)} \rightarrow CH_{4(g)}$

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Calculate the heat of formation for propene $(C_3H_6)$ using the following thermochemical equations:
$(i) C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H_1 = -94.05 \ k.cal/mole$
$(ii) H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(l)}; \Delta H_2 = -68.32 \ k.cal/mole$
$(iii) C_3H_{6(g)} + \frac{9}{2} O_{2(g)} \to 3 CO_{2(g)} + 3 H_2O_{(l)}; \Delta H_3 = -499.7 \ k.cal/mole$
(Note: The original question provided propane combustion data; assuming propene combustion data for consistency).

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Find the value of enthalpy of formation of $PCl_5(s)$ given the following thermochemical equations:
$1) \frac{1}{2} P_{4(s)} + 3Cl_{2(g)} \to 2PCl_3(\ell) ; \Delta H = -635 \ kJ$
$2) PCl_3(\ell) + Cl_{2(g)} \to PCl_{5(s)} ; \Delta H = -137 \ kJ$

In which of the following neutralisation reactions,the heat of neutralisation will be highest?

Which is the best definition of “heat of neutralization”?

The bond dissociation enthalpy of $X_2$,$\Delta H_{\text{bond}}^{\circ}$,calculated from the given data is $...$ $kJ \ mol^{-1}$. (Nearest integer)
$M^{+}X^{-}_{(s)} \rightarrow M^{+}_{(g)} + X^{-}_{(g)} \quad \Delta H_{\text{lattice}}^{\circ} = 800 \ kJ \ mol^{-1}$
$M_{(s)} \rightarrow M_{(g)} \quad \Delta H_{\text{sub}}^{\circ} = 100 \ kJ \ mol^{-1}$
$M_{(g)} \rightarrow M^{+}_{(g)} + e^{-}_{(g)} \quad \Delta H_{i}^{\circ} = 500 \ kJ \ mol^{-1}$
$X_{(g)} + e^{-}_{(g)} \rightarrow X^{-}_{(g)} \quad \Delta H_{\text{eg}}^{\circ} = -300 \ kJ \ mol^{-1}$
$M_{(s)} + \frac{1}{2}X_{2(g)} \rightarrow M^{+}X^{-}_{(s)} \quad \Delta H_{f}^{\circ} = -400 \ kJ \ mol^{-1}$
[Given : $M^{+}X^{-}$ is a pure ionic compound and $X$ forms a diatomic molecule $X_2$ in gaseous state]

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