$A$ given amount of $Fe^{2+}$ is oxidized by $x \ mol$ of $MnO_{4}^{-}$ in acidic medium. The number of moles of $Cr_{2}O_{7}^{2-}$ required to oxidize the same amount of $Fe^{2+}$ in acidic medium is

Which one of the following compounds does not decolourise an acidified aqueous solution of $KMnO_4$?

$I^{-}(aq.) + MnO_4^{-}(aq.) \xrightarrow{H^{+}} X + Mn^{2+}(aq.)$
$I^{-}(aq.) + MnO_4^{-}(aq.) \xrightarrow{\text{Neutral or weakly } OH^{-}} Y + MnO_2$
$MnO_4^{-}(aq.) + Mn^{2+}(aq.) \xrightarrow{ZnSO_4} Z + 4H^{+}$
Products $X, Y$ and $Z$ are respectively :

$X(aq.) + Na_2O_2 \to Y(aq.) \xrightarrow{BaCl_2} Z \downarrow_{\text{Insoluble in dil. } HCl}$
$X$ and $Y$ are different sodium salts. Then the anion present in the salt $(X)$ is:

Observe the following reactions:
$(i)$ $2 KClO_{3(s)} \xrightarrow{\Delta} 2 KCl_{(s)} + 3 O_{2(g)}$
$(ii)$ $2 H_2O_{2(aq)} \xrightarrow{\Delta} 2 H_2O_{(l)} + O_{2(g)}$
$(iii)$ $AgNO_{3(aq)} + KCl_{(aq)} \longrightarrow AgCl_{(s)} + KNO_{3(aq)}$
$(iv)$ $2 Na_{(s)} + \frac{1}{2} O_{2(g)} \longrightarrow Na_2O_{(s)}$
The number of redox reactions in this list is

The product $D$ in the following reaction sequence is: