$A$ certain reaction occurs in two steps as:
$(i)$ $2 SO_{2(g)} + 2 NO_{2(g)} \rightarrow 2 SO_{3(g)} + 2 NO_{(g)}$
$(ii)$ $2 NO_{(g)} + O_{2(g)} \rightarrow 2 NO_{2(g)}$
In the reaction,

  • A
    $NO_{2(g)}$ is intermediate
  • B
    $NO_{(g)}$ is intermediate
  • C
    $NO_{(g)}$ is catalyst
  • D
    $O_{2(g)}$ is intermediate

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Choose the correct statement regarding the formation of carbocations $A$ and $B$ given:
$CH_3-CH_2-CH=CH_2 + HBr \to CH_3-CH_2-CH_2-CH_2^+ + Br^-$ $(A)$
$CH_3-CH_2-CH=CH_2 + HBr \to CH_3-CH_2-CH^+-CH_3 + Br^-$ $(B)$

The most stable carbonium ion among the following is:

Which of the following carbocations is most stable?

The correct order of stability is:

The lower stability of ethyl anion compared to methyl anion and the higher stability of ethyl radical compared to methyl radical,respectively,are due to

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