$40 \ mL$ of a mixture of $CH_3COOH$ and $HCl$ (aqueous solution) is titrated against $0.1 \ M$ $NaOH$ solution conductometrically. Which of the following statements is correct?

  • A
    The concentration of $CH_3COOH$ in the original mixture is $0.005 \ M$
  • B
    The concentration of $HCl$ in the original mixture is $0.005 \ M$
  • C
    $CH_3COOH$ is neutralised first followed by neutralisation of $HCl$
  • D
    Point '$C$' indicates the complete neutralisation of $HCl$

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Similar Questions

In a conductometric titration,a small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration,and the conductance is measured after each addition.
The limiting ionic conductivity ( $\Lambda ^0$ ) values (in $mS \ m ^2 \ mol ^{-1}$ ) for different ions in aqueous solutions are given below:
Ions$Ag ^{+}$$K ^{+}$$Na ^{+}$$H ^{+}$$NO _3^{-}$$Cl ^{-}$$SO _4^{2-}$$OH ^{-}$$CH _3COO ^{-}$
$\Lambda _0$$6.2$$7.4$$5.0$$35.0$$7.2$$7.6$$16.0$$19.9$$4.1$

For different combinations of titrates and titrants given in List-$I$,the graphs of 'conductance' versus 'volume of titrant' are given in List-$II$.
List-$I$List-$II$
$(P)$ Titrate: $KCl$,Titrant: $AgNO _3$$(1)$ Graph showing initial decrease then increase
$(Q)$ Titrate: $AgNO _3$,Titrant: $KCl$$(2)$ Graph showing sharp decrease then sharp increase
$(R)$ Titrate: $NaOH$,Titrant: $HCl$$(3)$ Graph showing slight decrease then increase
$(S)$ Titrate: $NaOH$,Titrant: $CH _3COOH$$(4)$ Graph showing continuous increase
$(5)$ Graph showing decrease then constant

Match each entry in List-$I$ with the appropriate entry in List-$II$ and choose the correct option.

The amount of oxalic acid present in a solution can be determined by its titration with $KMnO_4$ solution in the presence of $H_2SO_4$. The titration gives an unsatisfactory result when carried out in the presence of $HCl$,because $HCl$:

Phenolphthalein is used as an indicator for the titration of sodium hydroxide solution against a standard solution of oxalic acid. The colour change that is observed at an alkaline pH close to the equivalence point during this titration is:

During the estimation of oxalic acid $Vs$ $KMnO_4$,the self-indicator is:

$110 \, mL$ of $0.1 \, N \, HCl$ is titrated with $30 \, mL$ of $0.2 \, N \, NaOH$. The remaining titration is completed by adding $0.25 \, N \, KOH$ solution. What volume of $KOH$ in $mL$ is required?

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