$Fe^{3+}$ cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of:

  • A
    $[Fe(H_2O)_6]_2[Fe(CN)_6]$
  • B
    $Fe_2[Fe(CN)_6]_2$
  • C
    $Fe_3[Fe(OH)_2(CN)_4]_2$
  • D
    $Fe_4[Fe(CN)_6]_3$

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When conc. $H_2SO_4$ is treated with $K_4[Fe(CN)_6]$,$CO$ gas is evolved. If dilute $H_2SO_4$ is used instead of conc. $H_2SO_4$,the gas evolved is:

What metal is present in Wilkinson's catalyst,which is used as a homogeneous catalyst for the hydrogenation of alkenes?

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$K_4[Fe(CN)_6] + ZnSO_4 \longrightarrow Zn_2[Fe(CN)_6] \downarrow + 2K_2SO_4$

$PCl_5$ reacts with finely divided silver on heating and a white silver salt is obtained,which dissolves on adding excess aqueous $NH_3$ solution. Write the reactions involved to explain what happens.

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