$C_3H_9N$ represents

You have been given four bottles marked $A, B, C$ and $D$ each containing one of the organic compounds given below:

$I: C_6H_5CH_2NH_2$	$II: C_6H_5CH_2COOH$
$III: C_6H_5CH_2CH_3$	$IV: C_6H_5CH_2CH(NH_2)COOH$

The following observations were made:
$(i)$ The compound in bottle $A$ did not dissolve in either $1 \ N \ NaOH$ or $1 \ N \ HCl$.
$(ii)$ The compound in bottle $B$ dissolved in $1 \ N \ NaOH$ but not in $1 \ N \ HCl$.
$(iii)$ The compound in bottle $C$ dissolved in both $1 \ N \ NaOH$ and $1 \ N \ HCl$.
$(iv)$ The compound in bottle $D$ did not dissolve in $1 \ N \ NaOH$ but dissolved in $1 \ N \ HCl$.
$(a)$ Indicate the compounds in: bottle $A = \dots$,bottle $B = \dots$,bottle $C = \dots$ and bottle $D = \dots$.
$(b)$ The compound with the highest solubility in distilled water is .......

Match List-$I$ with List-$II$ and select the correct answer.

List-$I$	List-$II$
$1.$ Aniline	$a.$ Used in the preparation of azo dyes
$2.$ Nitrobenzene	$b.$ Sulpha drug
$3.$ Sulphanilamide	$c.$ Solvent in Friedel-Crafts reaction
$4.$ Trinitrotoluene	$d.$ Used as an explosive

An alkyl halide reacts with alcoholic ammonia in a sealed tube,the product formed will be

$Ph-NH_2$ $\xrightarrow{CH_3Cl \ (2 \ mole)} (A)$ $\xrightarrow{Ph-N_2^+ Cl^-} (B) \ (\text{major})$
Butter yellow is the product of the above reaction.

Primary and secondary amines are distinguished by
$(i)$ Hinsberg test
$(ii)$ Carbyl amine test
$(iii)$ Hofmann mustard oil test
$(iv)$ $HNO_2$ test