What are the products formed by the reaction of phenol with dilute $HNO_3$? By which method are these products separated,and what is the name of the compound that separates out and the reason for it?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $(i)$ Nitration of phenol with dilute $HNO_3$ yields a mixture of $o$-nitrophenol and $p$-nitrophenol.
$(ii)$ The components of this nitrophenol mixture are separated by the steam distillation method.
$(iii)$ Upon steam distillation of the mixture of $o$- and $p$-nitrophenol,$o$-nitrophenol distills over with steam and is separated,while $p$-nitrophenol remains in the flask.
$(iv)$ $o$-nitrophenol is volatile with steam due to the presence of intramolecular hydrogen bonding,allowing it to be separated.
$p$-nitrophenol is less volatile in steam distillation and remains in the flask because it exhibits intermolecular $H$-bonding,as shown below.

Explore More

Similar Questions

Which of the following is the weakest acid?

In the given reaction: $[X] +$ Acetic anhydride $\rightarrow$ Aspirin,$[X]$ will be:

What are $X$ and $Y$ in the following reactions?

The heating of phenyl methyl ether with $HI$ produces an aromatic compound $A$ which on treatment with conc. $HNO_3$ gives $B$. $A$ and $B$ respectively are

What are $X$ and $Y$ respectively in the following set of reactions?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo