Describe the electrophilic aromatic substitution reactions of phenol.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Phenol undergoes electrophilic aromatic substitution reactions due to the activating effect of the $-OH$ group,which directs incoming electrophiles to the ortho and para positions.
$1$. Nitration:
- With dilute $HNO_3$ at $298 \ K$,phenol gives a mixture of $o$-nitrophenol and $p$-nitrophenol.
- With concentrated $HNO_3$,phenol is converted into $2,4,6$-trinitrophenol,commonly known as picric acid.
$2$. Sulphonation:
- Phenol reacts with concentrated $H_2SO_4$ to form $o$-phenolsulphonic acid at low temperature $(293 \ K)$ and $p$-phenolsulphonic acid at higher temperature $(373 \ K)$.

Explore More

Similar Questions

Phenol is heated with a solution of a mixture of $KBr$ and $KBrO_3$. The major product obtained in the above reaction is:

For phenol,which of the following statements is correct?

Which one of the following is most reactive towards electrophilic attack?

Difficult
View Solution

The reaction sequence is as follows: $C_6H_5SO_3H$ $\xrightarrow[(ii) H^+]{(i) NaOH} P$ $\xrightarrow{Na_2Cr_2O_7, H_2SO_4} Q$. The ratio of $\sigma$ bonds to $\pi$ bonds in $Q$ is:

Which of the following phenols has the largest $pK_a$ value (i.e.,is least acidic)?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo