$2.2016 \ g$ of acetaldehyde produced $13.95 \ kcal$ of heat on combustion in $O_2$. Calculate the heat of combustion of $CH_3CHO$ in $kcal \ mol^{-1}$.

$C_{(diamond)} + O_2 \to CO_2; \Delta H = -395.3 \ kJ/mole$
$C_{(graphite)} + O_2 \to CO_2; \Delta H = -393.4 \ kJ/mole$
$C_{(graphite)} \to C_{(diamond)}; \Delta H = ?$

In which of the following reactions does the heat change represent the heat of formation of water?

If bond energy for $H_{2(g)}$,$Br_{2(g)}$ and $HBr_{(g)}$ is $433$,$192$ and $364 \ kJ \ mol^{-1}$ respectively,then $\Delta H^o$ for the reaction,$H_{2(g)} + Br_{2(g)} \to 2HBr_{(g)}$ is......$kJ$.

Consider the following data:
Heat of combustion of $H_{2(g)} = -241.8 \ kJ \ mol^{-1}$
Heat of combustion of $C_{(s)} = -393.5 \ kJ \ mol^{-1}$
Heat of combustion of $C_2H_5OH_{(l)} = -1234.7 \ kJ \ mol^{-1}$
The heat of formation of $C_2H_5OH_{(l)}$ is $(-)$ $...... \ kJ \ mol^{-1}$ (Nearest integer).

The bond dissociation enthalpies of $H_2$,$Cl_2$,and $HCl$ are $434$,$242$,and $431 \ kJ \ mol^{-1}$ respectively. What is the enthalpy of formation of $HCl$ in $kJ \ mol^{-1}$?