Which of the following is correct?

  • A
    $[dG/dP]_T = V$
  • B
    $[dG/dT]_P = -S$
  • C
    $[dG/dP]_T = 1/V$
  • D
    $[dG/dT]_P = C_V$

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For an endothermic reaction at constant temperature $T$ and pressure $P$,if the process is spontaneous,which of the following is true?

For the reaction $H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}$,$\Delta H = -285.8 \ kJ \ mol^{-1}$,$\Delta S = -0.163 \ kJ \ mol^{-1} K^{-1}$. What is the value of free energy change at $27 \ ^\circ C$ for the reaction in $kJ \ mol^{-1}$?

For a chemical reaction,if $\Delta H > 0$ and $\Delta S > 0$,under what condition will the reaction not be spontaneous?

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