The reaction of methanol $(\Delta H_f^o = -238.7 \ kJ \ mol^{-1})$ with $2$-methylpropene produces methyl tert-butyl ether $(\Delta H_f^o = -313.6 \ kJ \ mol^{-1})$. Given the reaction: $(CH_3)_2C = CH_2 + CH_3OH \rightarrow (CH_3)_3C - OCH_3; \Delta H^o = -57.8 \ kJ \ mol^{-1}$,calculate the $\Delta H_f^o$ for $2$-methylpropene.

  • A
    $-17.1 \ kJ \ mol^{-1}$
  • B
    $23.4 \ kJ \ mol^{-1}$
  • C
    $8.6 \ kJ \ mol^{-1}$
  • D
    $-20.68 \ kJ \ mol^{-1}$

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The heat of reaction does not depend upon

Two reactions are given below:
$2 Fe_{(s)} + \frac{3}{2} O_{2_{(g)}} \rightarrow Fe_2 O_{3_{(s)}}, \Delta H^{o} = -822 \ kJ/mol$
$C_{(s)} + \frac{1}{2} O_{2_{(g)}} \rightarrow CO_{(g)}, \Delta H^{o} = -110 \ kJ/mol$
Then,the enthalpy change for the following reaction is:
$3 C_{(s)} + Fe_2 O_{3_{(s)}} \rightarrow 2 Fe_{(s)} + 3 CO_{(g)}$

What is the heat of formation of $HCl_{(g)}$ from the following equation (in $kJ$)?
$H_{2(g)} + Cl_{2(g)} \rightarrow 2HCl_{(g)} \quad \Delta_{r}H = -194 \ kJ$

Find the value $\Delta H_f^o[NH_{3(g)}]$ if $\Delta H_r$ for the reaction $N_{2(g)} + 3H_{2(g)} \to 2NH_{3(g)}$ is $-\,183.6 \ kJ/mol$ of $N_{2(g)}$.

If the enthalpy of formation of $N_2O$ is $82 \, kJ \, mol^{-1}$,calculate the resonance energy of $N_2O$ in $kJ \, mol^{-1}$.
$N \equiv N \, (946 \, kJ \, mol^{-1}); \, N = N \, (418 \, kJ \, mol^{-1})$
$O = O \, (498 \, kJ \, mol^{-1}); \, N = O \, (607 \, kJ \, mol^{-1})$

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