For the reaction $Br_2 \rightleftharpoons 2Br$,the equilibrium constants at $327\,^oC$ and $527\,^oC$ are $6.1 \times 10^{-12}$ and $1.0 \times 10^{-7}$ respectively. The reaction is ...........

  • A
    Endothermic
  • B
    Exothermic
  • C
    Isothermal
  • D
    Cannot be predicted

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For the equilibrium $ \text{Liquid} \rightleftharpoons \text{Vapour} $,which of the following expressions is correct?

In a $10 \ L$ vessel,$1 \ mol$ each of $PCl_5$ and $PCl_3$ are present. If the vessel is heated,some $PCl_5$ dissociates. What are the concentrations of $PCl_5$,$PCl_3$,and $Cl_2$ at equilibrium,respectively?

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For the reaction $I_{2(g)} \rightleftharpoons 2I_{(g)}$,the equilibrium constant $K_c$ at $1000 \ K$ is $10^{-6}$. If $1 \ mol$ of $I_2$ is added to a $1 \ L$ container,which of the following statements is true at equilibrium?

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At $473 \ K$,the equilibrium constant $K_{c}$ for the decomposition of phosphorus pentachloride is $8.3 \times 10^{-3}$. If the decomposition is depicted as:
$PCl_{5(g)} \longleftrightarrow PCl_{3(g)} + Cl_{2(g)} \quad \Delta_{r}H^{\circ} = 124.0 \ kJ \ mol^{-1}$
$(a)$ Write an expression for $K_{c}$ for the reaction.
$(b)$ What is the value of $K_{c}$ for the reverse reaction at the same temperature?
$(c)$ What would be the effect on $K_{c}$ if:
$(i)$ more $PCl_{5}$ is added?
$(ii)$ pressure is increased?
$(iii)$ the temperature is increased?

At a certain temperature and total pressure of $10^{5} \ Pa$,iodine vapour contains $40 \%$ by volume of $I$ atoms.
$I_{2(g)} \longleftrightarrow 2I_{(g)}$
Calculate $K_{p}$ for the equilibrium.

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