$X + H_2SO_4 \to Y$ (a colorless gas with a pungent smell).
$Y + K_2Cr_2O_7 + H_2SO_4 \to$ green colored solution.
What are $X$ and $Y$?

  • A
    $SO_3^{2-}, SO_2$
  • B
    $Cl^-, HCl$
  • C
    $S^{2-}, H_2S$
  • D
    $CO_3^{2-}, CO_2$

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$A$ white crystalline salt $A$ reacts with dilute $HCl$ to liberate a suffocating gas $B$ and also forms a yellow precipitate. The gas $B$ turns potassium dichromate acidified with dilute $H_{2}SO_{4}$ to a green coloured solution $C$. $A$,$B$ and $C$ are respectively

Match List-$I$ with List-$II$:
List-$I$ (Anion) List-$II$ (Gas evolved on reaction with dil. $H_2SO_4$)
$A. CO_3^{2-}$ $I$. Colourless gas which turns lead acetate paper black
$B. S^{2-}$ $II$. Colourless gas which turns acidified potassium dichromate solution green
$C. SO_3^{2-}$ $III$. Brown fumes which turn acidified $KI$ solution containing starch blue
$D. NO_2^{-}$ $IV$. Colourless gas evolved with brisk effervescence,which turns lime water milky

Choose the correct answer from the options given below:

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