$AgNO_3 \xrightarrow{\Delta} (W) + (X) + O_2$
$(X) + H_2O \to HNO_2 + HNO_3$
$(W) + HNO_3 \to (Y) + NO + H_2O$
$(Y) + Na_2S_2O_3 (\text{excess}) \to (Z) + NaNO_3$
Identify $(W)$ to $(Z)$.

  • A
    $W = Ag, X = N_2O, Y = AgNO_3, Z = Na_2[Ag(S_2O_3)_2]$
  • B
    $W = Ag_2O, X = NO, Y = AgNO_3, Z = Na_3[Ag(S_2O_3)_2]$
  • C
    $W = Ag, X = NO_2, Y = AgNO_3, Z = Na_3[Ag(S_2O_3)_2]$
  • D
    $W = Ag_2O, X = N_2, Y = AgNO_3, Z = Na[Ag(S_2O_3)_2]$

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