Write the Nernst equation for the $E_{cell}$ of a Daniell cell.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The Daniell cell reaction is given by: $Zn(s) + Cu^{2+}(aq) \rightarrow Zn^{2+}(aq) + Cu(s)$.
For this cell,the Nernst equation at $298 \ K$ is expressed as:
$E_{cell} = E^{\circ}_{cell} - \frac{0.0591}{n} \log \frac{[Zn^{2+}]}{[Cu^{2+}]}$.
Here,$n = 2$ (number of electrons transferred in the redox reaction).
Thus,the equation becomes: $E_{cell} = E^{\circ}_{cell} - \frac{0.0591}{2} \log \frac{[Zn^{2+}]}{[Cu^{2+}]}$.

Explore More

Similar Questions

The cell potential for the following cell notation is approximately
$M_{(s)} | M^{3+}(aq, 0.01 \ M) || N^{2+}(aq, 0.1 \ M) | N_{(s)}$
$E_{M^{3+} / M}^0 = 0.6 \ V$ and $E_{N^{2+} / N}^0 = 0.1 \ V$ (in $V$)

Consider the cell $Pt | H_2(P_1 \ atm) | H^{+}(X_1 \ M) || H^{+}(X_2 \ M) | H_2(P_2 \ atm) | Pt$. The cell reaction will be spontaneous if

The cell reaction of the given cell is spontaneous if:
$Pt | Cl_2 (P_1 \, atm) | Cl^{-} (1 \, M) || Cl^{-} (1 \, M) | Cl_2 (P_2 \, atm) | Pt$

Difficult
View Solution

If a hydrogen electrode is dipped in two solutions of $pH = 3$ and $pH = 6$ and a salt bridge is connected,the e.m.f. of the resulting cell is ............ $V$.

The $emf$ (in $V$) of a $Daniell$ cell containing $0.1 \ M \ ZnSO_4$ and $0.01 \ M \ CuSO_4$ solutions at their respective electrodes is $\left(E_{Cu^{2+} / Cu}^{\circ}=+0.34 \ V ; E_{Zn^{2+} / Zn}^{\circ}=-0.76 \ V\right)$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo