What is a zero order reaction? Determine the integrated rate equation for a zero order reaction $R \to P$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
$A$ zero order reaction is a reaction in which the rate of reaction is proportional to the zero power of the concentration of reactants.
$\therefore \text{Rate} \propto [R]^{0}$
For the given reaction $R \to P$,which is a zero order reaction,the differential rate expression is:
$\text{Rate} = -\frac{d[R]}{dt} = k[R]^{0}$
Since $[R]^{0} = 1$,we have:
$-\frac{d[R]}{dt} = k \quad \dots (i)$
Rearranging the equation:
$d[R] = -k dt \quad \dots (ii)$
Integrating both sides:
$[R] = -kt + I \quad \dots (iii)$
where $I$ is the constant of integration.
At $t = 0$,the concentration of the reactant $[R] = [R]_{0}$,where $[R]_{0}$ is the initial concentration.
Substituting these values into equation $(iii)$:
$[R]_{0} = (-k \times 0) + I$
$\therefore I = [R]_{0} \quad \dots (iv)$
Substituting the value of $I$ back into equation $(iii)$:
$[R] = -kt + [R]_{0}$
Rearranging to solve for $k$:
$kt = [R]_{0} - [R]$
$\therefore k = \frac{[R]_{0} - [R]}{t}$

Explore More

Similar Questions

The rate constant for a zero order reaction is $2 \times 10^{-2} \ mol \ L^{-1} s^{-1}$. If the concentration of the reactant after $25 \ s$ is $0.5 \ M$,the initial concentration must have been $:-$ (in $M$)

For a zero order reaction $A \longrightarrow \text{product}$,the concentration of $A$ decreases from $0.8 \ mol \ dm^{-3}$ to $0.2 \ mol \ dm^{-3}$ in $6 \ minute$. What is the rate constant of the reaction?

If the initial concentration of a reactant is $a$,how much time will it take for a $100\%$ zero-order reaction to complete?

Consider the reaction $aX \to bY$,for which the rate constant at $30^\circ C$ is $1 \times 10^{-3} \text{ mol L}^{-1} \text{ s}^{-1}$. Which of the following statements are true?
$A$. When concentration of $X$ is increased to four times,the rate of reaction becomes $16$ times.
$B$. The reaction is a second order reaction.
$C$. The half-life period is independent of the concentration of $X$.
$D$. Decomposition of $N_2O_5$ is an example of the above reaction.
$E$. $\ln \frac{[R]_0}{[R]}$ vs time is valid for the above reaction.

For the reaction $R \rightarrow P$,the concentration of $R$ is measured as a function of time and the following data is obtained:
$[R] \ (M)$ $1.0$ $0.76$ $0.40$ $0.10$
$t \ (min)$ $0.0$ $0.05$ $0.12$ $0.18$

The order of the reaction is:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo