What is a first-order reaction? Determine the integrated rate equation for a first-order reaction $R \to P$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) First-order reaction: $A$ reaction in which the rate of reaction is proportional to the first power of the concentration of the reactant $R$ is called a first-order reaction.
The rate of a first-order reaction $\propto [R]^1$.
For the reaction $R \to P$,the differential rate expression is:
$Rate = -\frac{d[R]}{dt} = k[R]$
$\therefore \frac{d[R]}{[R]} = -k dt \dots (i)$
Integrating this equation on both sides:
$\int \frac{d[R]}{[R]} = -\int k dt$
$\ln [R] = -kt + I \dots (ii)$
Here,$I$ is the constant of integration.
When $t = 0$,$[R] = [R]_0$,where $[R]_0$ is the initial concentration of the reactant. Substituting these values into equation $(ii)$:
$\ln [R]_0 = -k(0) + I \implies I = \ln [R]_0 \dots (iii)$
Substituting $I = \ln [R]_0$ into equation $(ii)$:
$\ln [R] = -kt + \ln [R]_0 \dots (iv)$
Rearranging the terms:
$kt = \ln [R]_0 - \ln [R]$
$kt = \ln \frac{[R]_0}{[R]}$
$k = \frac{1}{t} \ln \frac{[R]_0}{[R]} \dots (v)$
Converting to base $10$ logarithm:
$k = \frac{2.303}{t} \log \frac{[R]_0}{[R]} \dots (vi)$
Taking the antilog of equation $(iv)$,we get:
$[R] = [R]_0 e^{-kt} \dots (vii)$

Explore More

Similar Questions

$R \rightarrow P$ is a first order reaction. For this reaction,a graph of $\ln [R]$ (on $y$-axis) and time (on $x$-axis) gives a straight line with a negative slope. The intercept on the $y$-axis is equal to ($k =$ rate constant):

The unit of the specific reaction rate constant for a first-order reaction (if the concentration is expressed in molarity) is:

For the reaction $2A + B \to \text{product}$,the rate law is given by $\frac{-d[A]}{dt} = k[A]$. At a time $t = \frac{t_{1/2}}{\ln 2}$,what is the concentration of the reactant $A$?

For a homogeneous gaseous reaction $A_{(g)} \to 3B_{(g)}$,if the pressure after time $t$ is $P_t$ and after completion of the reaction the pressure is $P_\infty$,select the correct relation for the rate constant $K$.

Difficult
View Solution

In a first order reaction $A \to B,$ if $k$ is the rate constant and the initial concentration of the reactant $A$ is $0.5 \ M,$ then the half-life is:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo