For silver,$C_P \, (J \, K^{-1} \, mol^{-1}) = 23 + 0.01 \, T$. If the temperature $(T)$ of $3 \, moles$ of silver is raised from $300 \, K$ to $1000 \, K$ at $1 \, atm$ pressure,the value of $\Delta H$ will be close to $kJ$.

  • A
    $13$
  • B
    $62$
  • C
    $16$
  • D
    $21$

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For the reaction $CO_{(g)} + \frac{1}{2}O_{2_{(g)}} \rightarrow CO_{2_{(g)}}$ at $17^o C$ and constant volume,the heat of reaction is $-67.71 \, K \, cal$. What is the heat of reaction at constant pressure at $17^o C$ in $K \, cal$?

In a reversible process,under what condition does the heat exchanged become a state function?

Match the conditions and the temperature for the 'fusion' process of $H_2O_{(s)}$ at $1 \ atm$ pressure.
Condition Temperature
$(1)$. Spontaneous $(p)$. $273 \ K$
$(2)$. At equilibrium $(q)$. $260 \ K$
$(3)$. Non-spontaneous $(r)$. $280 \ K$

Given the following thermochemical equations:
$(i) S_{(s)} + \frac{3}{2} O_{2(g)} \rightarrow SO_{3(g)} + 2x \, kcal$
$(ii) SO_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow SO_{3(g)} + y \, kcal$
Find the heat of formation of $SO_{2(g)}$.

$A$ solution of $500 \ mL$ of $2 \ M \ KOH$ is added to $500 \ mL$ of $2 \ M \ HCl$ and the mixture is well shaken. The rise in temperature $T_1$ is noted. The experiment is then repeated using $250 \ mL$ of each solution and the rise in temperature $T_2$ is again noted. Assume all heat is absorbed by the solution.

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