Explain why the electron gain enthalpy of fluorine is less negative than that of chlorine.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The electron gain enthalpy of fluorine is less negative than that of chlorine due to its small atomic size.
In fluorine,the incoming electron experiences significant inter-electronic repulsion because the $2p$ orbitals are compact.
In contrast,chlorine has a larger atomic size and the incoming electron enters the $3p$ orbital,which has more space available.
This results in less inter-electronic repulsion in chlorine,making the process more exothermic and leading to a more negative electron gain enthalpy compared to fluorine.

Explore More

Similar Questions

The electron affinity values (in $kJ \ mol^{-1}$) for halogens $X, Y,$ and $Z$ are $-349, -333,$ and $-325$ respectively. Therefore,$X, Y,$ and $Z$ are respectively which of the following?

Which of the following has the highest electron affinity $(EA)$?

To which of the following atoms is the attachment of an electron most difficult?

Which of the following arrangements for the three halogens $Cl$,$Br$,and $I$ when placed in the order of their increasing electron affinity is correct?

Electron gain enthalpy values $(\Delta_{eg} H)$ (in $kJ \ mol^{-1}$) of elements $X$,$Y$ and $Z$ are $-349$,$-200$ and $-295$ respectively. $X$,$Y$ and $Z$ are respectively

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo