Explain the principle and estimation method for carbon and hydrogen in an organic compound.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Principle: Carbon and hydrogen in an organic compound are estimated by burning a known mass of the compound in the presence of excess oxygen and copper $(II)$ oxide $(CuO)$. Carbon is oxidized to carbon dioxide $(CO_2)$ and hydrogen is oxidized to water $(H_2O)$.
Reaction: $C_xH_y + (x + \frac{y}{4})O_2 \rightarrow xCO_2 + \frac{y}{2}H_2O$
Procedure:
$1$. $A$ known mass $(m \ g)$ of the organic compound is placed in a platinum boat and burnt in a combustion tube in the presence of excess oxygen and $CuO$.
$2$. The resulting gases are passed through a weighed $U$-tube containing anhydrous calcium chloride $(CaCl_2)$,which absorbs water.
$3$. The gases are then passed through another weighed $U$-tube containing a concentrated solution of potassium hydroxide $(KOH)$,which absorbs carbon dioxide.
Calculation:
- Let the increase in mass of the $CaCl_2$ $U$-tube be $m_1 \ g$ (mass of $H_2O$ produced).
- Let the increase in mass of the $KOH$ $U$-tube be $m_2 \ g$ (mass of $CO_2$ produced).
Percentage of Hydrogen: Since $18 \ g$ of $H_2O$ contains $2 \ g$ of hydrogen,
$\text{Percentage of } H = \frac{2 \times m_1 \times 100}{18 \times m}$
Percentage of Carbon: Since $44 \ g$ of $CO_2$ contains $12 \ g$ of carbon,
$\text{Percentage of } C = \frac{12 \times m_2 \times 100}{44 \times m}$

Explore More

Similar Questions

Explain the principle of estimation of oxygen in an organic compound.

Difficult
View Solution

Which of the following substances cannot be analyzed using the Kjeldahl method for the estimation of nitrogen?

State True or False for the following statements:
$(i)$ The volume of $N_2$ is measured by nitrometer.
$(ii)$ The weight of $N_2$ is measured by nitrometer.
$(iii)$ The weight of $NH_3$ is measured by nitrometer.
$(iv)$ The volume of $NH_3$ is measured by nitrometer.

$0.5 \ g$ of an organic compound containing phosphorus was heated with conc. $HNO_3$ in a Carius tube. The phosphoric acid thus formed was precipitated with magnesia mixture $[MgNH_4PO_4]$,which on ignition gave a residue of $1.0 \ g$ of magnesium pyrophosphate $(Mg_2P_2O_7)$. The percentage of phosphorus in the organic compound is:

Difficult
View Solution

In the sulphur estimation,$0.20 \ g$ of a pure organic compound gave $0.40 \ g$ of barium sulphate. The percentage of sulphur in the compound is $.......... \times 10^{-1} \%$. $(Molar \ mass : O=16, S=32, Ba=137 \ g \ mol^{-1})$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo