Define the electromeric effect and describe its types.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Definition: The electromeric effect is a temporary effect observed in organic compounds containing multiple bonds (double or triple bonds) in the presence of an attacking reagent. It is defined as the complete transfer of a shared pair of $\pi$-electrons to one of the atoms joined by a multiple bond at the demand of an attacking reagent.
Characteristics:
$1$. It is a temporary effect and is annulled as soon as the attacking reagent is removed.
$2$. It is represented by $E$ and the electron shifting is shown by a curved arrow $(\curvearrowleft)$.
Types of Electromeric Effect:
$(a)$ Positive Electromeric Effect $(+E)$: In this effect,the $\pi$-electrons of the multiple bond are transferred to the atom to which the attacking reagent gets attached. Example: Addition of $H^+$ to an alkene.
$(b)$ Negative Electromeric Effect $(-E)$: In this effect,the $\pi$-electrons of the multiple bond are transferred to the atom to which the attacking reagent does $NOT$ get attached. Example: Addition of $CN^-$ to a carbonyl group.

Explore More

Similar Questions

Which of the following compounds has the maximum enol content?

Difficult
View Solution

Which among the given acids has the lowest $pKa$ value?

Which of the following orders correctly depicts the decreasing order of stability of carbanion?

What is a conjugated system? Give examples and explain its effect.

Rank the following compounds in the order of increasing acidic strength:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo