Bond which is formed by sidewise overlapping | vedclass

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Question

(B) The sidewise overlapping of $p$-orbitals leads to the formation of a $\pi$-bond. In the given options,we look for a species containing a $p\pi-p\p

Vedclass · Accepted Answer

$CS_3^{2-}$

Vedclass · Answer

(B) The sidewise overlapping of $p$-orbitals leads to the formation of a $\pi$-bond. In the given options,we look for a species containing a $p\pi-p\pi$ bond involving a chalcogen (Group $16$) atom. In $CS_3^{2-}$ (trithiocarbonate ion),the structure involves a central carbon atom double-bonded to sulfur atoms. The $C=S$ bond is formed by the sidewise overlapping of the $2p$-orbital of carbon and the $2p$-orbital of sulfur. Therefore,$CS_3^{2-}$ contains a bond formed by the sidewise overlapping of $2p$-orbitals.

Bond which is formed by sidewise overlapping of $2p$-orbitals of chalcogen atom is present in :

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